SYNTHESIS AND REACTIONS OF AZIDO COMPLEXES OF RUTHENIUM

被引：17

作者：

BUYS, IE ^{[1
]}

FIELD, LD ^{[1
]}

GEORGE, AV ^{[1
]}

HAMBLEY, TW ^{[1
]}

PURCHES, GR ^{[1
]}

机构：

[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 01期

关键词：

D O I：

10.1071/CH9950027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sodium azide reacts with RuH2 (dmpe)(2) (1a) (dmpe = 1,2-bis(dimethylphosphino)ethane) in methanol solution to form RuH(N-3)(dmpe)(2) (2a), and reacts with RuCl2(depe)(2) (3b) (depe = 1,2-bis(diethylphosphino)ethane) to form the bis(azide) complex Ru(N-3)(2)(depe)(2) (4b). The crystal structures of Ru(Cl)(2)(depe)(2) (3b) and Ru(N-3)(2)(depe)(2) (4b) have been determined and indicate that the chloro groups in (3b) and the azido groups in (4b) are trans across the metal centre.

引用

页码：27 / 34

页数：8

共 34 条

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