THIONE S-IMIDES - REACTION WITH THE CARBON-CARBON DOUBLE-BOND - 1,3-DIPOLAR AND DIELS-ALDER-TYPE CYCLO-ADDITION AND ENE REACTIONS

被引：25

作者：

SAITO, T ^{[1
]}

MOTOKI, S ^{[1
]}

机构：

[1] SCI UNIV TOKYO,FAC SCI,DEPT CHEM,SHINJUKU KU,TOKYO 162,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 14期

关键词：

D O I：

10.1021/jo01328a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thione S-imide (1) reacted as a 1, 3 dipole with enamine (5), vinyl ethers (2), bicyclo olefins (10, 12), and cyclopentadiene (18) to give 1, 3 dipolar cycloadducts, while with acyclic dienes (14) the imide reacted as a dienophile to give Diels-Alder-type cycloadducts. Furthermore, the imide and (1-cyclohexenyl)amines (7) afforded ene-reaction products. © 1979, American Chemical Society. All rights reserved.

引用

页码：2493 / 2498

页数：6

共 38 条

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[J]. ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1977, 31 (10): : 890 - 894
[8] CYCLOADDITION REACTIONS OF VINYL SULFENE GENERATED FROM THIETE 1,1-DIOXIDE
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (11) : 1910 - 1913
[9] FINDLAY DM, 1972, CAN J CHEM, V50, P3186
[10] GUNTHER H, 1977, CHEM REV, V77, P599

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