PHOTOLYSIS OF 1,1,1-TRIARYLALKANE - A NEW PHOTOCHEMICAL CARBENE GENERATION PROCESS

被引：8

作者：

SHI, M ^{[1
]}

OKAMOTO, Y ^{[1
]}

TAKAMUKU, S ^{[1
]}

机构：

[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 12期

关键词：

D O I：

10.1021/jo00299a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Upon UV irradiation in methanol, some 1,1,1-triarylalkanes underwent an a,a-elimination of two aryl groups to give biaryls and the corresponding carbene intermediates, which inserted into the OH bond of the methanol to afford methyl ethers and/or underwent a 1,2-H shift to afford olefins. Furthermore, the efficiency of this elimination was highly dependent upon the bulkiness of the alkyl groups. © 1990, American Chemical Society. All rights reserved.

引用

页码：3821 / 3824

页数：4

共 20 条

[1] CYCLOPROPYL ANALOGS OF HEXESTROL AND DIETHYLSTILBESTROL [J].