PREDICTED CHAIN CONFORMATION FOR A POSSIBLE PHASE-III FORM OF POLY(VINYLIDENE FLUORIDE)

被引:22
作者
TRIPATHY, SK
POTENZONE, R
HOPFINGER, AJ
BANIK, NC
TAYLOR, PL
机构
[1] CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106
[2] CASE WESTERN RESERVE UNIV,DEPT PHYS,CLEVELAND,OH 44106
关键词
D O I
10.1021/ma60070a019
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Intramolecular conformational analysis of PVF2 suggests two possible chain conformations for a form of this material identified as phase III by Lando and co-workers. The two chain conformations are perturbations of TTTGTTTG' and TGTG ‘TG’ TG. Both are consistent with X-ray data. Although TTTGTTTG' is preferred on the basis of intrachain molecular energetics and FTIR data, it is not possible to select between these two conformations. © 1979, American Chemical Society. All rights reserved.
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页码:656 / 658
页数:3
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