FUNCTIONALIZATION OF SILICA-GEL - APPLICATION FOR THE CATALYTIC-OXIDATION OF ALKANES

被引：39

作者：

KURUSU, Y ^{[1
]}

NECKERS, DC ^{[1
]}

机构：

[1] BOWLING GREEN STATE UNIV,CTR PHOTOCHEM SCI,BOWLING GREEN,OH 43403

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 06期

关键词：

D O I：

10.1021/jo00006a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silica gel, functionalized by N,N-dimethyl-3-aminopropyl)trimethoxysilane and complexed with Fe-(II) or other metal ions in the presence of O2 was effective for the aerobic, room temperature oxidation of a C-H bond in cyclohexane. The products were cyclohexanol and cyclohexanone.

引用

页码：1981 / 1983

页数：3

共 15 条

[1] Barton D. H. R., 1989, ACTIVATION FUNCTIONA, P281
[2] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .4. THE GIF SYSTEM FOR SELECTIVE OXIDATION USING MOLECULAR-OXYGEN
BARTON, DHR
BOIVIN, J
GASTIGER, M
MORZYCKI, J
HAYMOTHERWELL, RS
MOTHERWELL, WB
OZBALIK, N
SCHWARTZENTRUBER, KM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (06): : 947 - 955
[3] A NEW AND EFFICIENT BIOMIMETIC SYSTEM FOR HYDROCARBON OXIDATION BY DIOXYGEN USING MANGANESE PORPHYRINS, IMIDAZOLE, AND ZINC
BATTIONI, P
BARTOLI, JF
LEDUC, P
FONTECAVE, M
MANSUY, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (10) : 791 - 792
[4] THE ORGANOMETALLIC CHEMISTRY OF ALKANES
CRABTREE, RH
[J]. CHEMICAL REVIEWS, 1985, 85 (04) : 245 - 269
[5] STRUCTURAL CHARACTERIZATION BY EXAFS SPECTROSCOPY OF THE BINUCLEAR IRON CENTER IN PROTEIN-A OF METHANE MONOOXYGENASE FROM METHYLOCOCCUS-CAPSULATUS (BATH)
ERICSON, A
HEDMAN, B
HODGSON, KO
GREEN, J
DALTON, H
BENTSEN, JG
BEER, RH
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) : 2330 - 2332
[6] FOX BG, 1988, J BIOL CHEM, V263, P10553
[7] JIN RH, UNPUB J POLYM SCI A
[8] KAYL GW, 1973, TABLES PHYSICAL CHEM, P225
[9] KHENKIN AM, 1989, NEW J CHEM, V13, P669
[10] A MODEL FOR METHANE MONO-OXYGENASE - DIOXYGEN OXIDATION OF ALKANES BY USE OF A MU-OXO BINUCLEAR IRON COMPLEX
KITAJIMA, N
FUKUI, H
MOROOKA, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (07) : 485 - 486

← 1 2 →