MOLECULAR SIMULATION OF THE ENTHALPIES OF ARGON(1)+METHANE(2) AT DIFFERENT TEMPERATURES AND PRESSURES

被引：4

作者：

GUO, MX ^{[1
]}

LI, YG ^{[1
]}

WANG, WC ^{[1
]}

LU, HZ ^{[1
]}

机构：

[1] BEIJING INST CHEM TECHNOL,DEPT CHEM ENGN,BEIJING 100029,PEOPLES R CHINA

来源：

THERMOCHIMICA ACTA | 1993年 / 221卷 / 02期

关键词：

D O I：

10.1016/0040-6031(93)85060-M

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The Gibbs-ensemble Monte Carlo simulation method was applied to calculate the enthalpies of the argon (1) + methane (2) system at 150.72 and 164.0 K. The Lennard-Jones (LJ) potential function was adopted to describe the intermolecular interactions. Three hundred spherical, isotropic particles were used in all simulation runs. A new particle transfer method is proposed that has been found to be more efficient than the random insertion method. A satisfactory agreement was obtained between our simulation results and the predictions by the Soave and Peng-Robinson equations of state (EOSs).

引用

页码：163 / 170

页数：8

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