QUANTUM CORRECTIONS TO THE CLASSICAL PATH THEORY

被引:84
作者
BILLING, GD
机构
[1] Department of Chemistry, H. C. ØRsted Institute, University of Copenhagen
关键词
D O I
10.1063/1.465938
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss an effective numerical method for obtaining the best trajectory to be used in the classical path approach. The method is based upon a time dependent variational method, which yields from first principles the classical path equations. In its simplest formulation the classical path equations contain an optimal momentum determined self-consistently. A variational method, which satisfies detailed balance is also discussed.
引用
收藏
页码:5849 / 5857
页数:9
相关论文
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