ORGANOALUMINUM-PROMOTED HOMOLOGATION OF KETONES WITH DIAZOALKANES

被引：46

作者：

MARUOKA, K ^{[1
]}

CONCEPCION, AB ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] NAGOYA UNIV,SCH ENGN,CHIKUSA KU,NAGOYA 46401,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 17期

关键词：

D O I：

10.1021/jo00096a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organoaluminum-promoted single homologation of aliphatic and aromatic ketones with diazoalkanes has been described, and among various organoaluminum reagents, especially bulky methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is found to be highly effective for the selective homologation of various ketones.

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页码：4725 / 4726

页数：2

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