BEHAVIOR OF PURE DIVALENT BIS(DIDODECYLDIMETHYLAMMONIUM) BIS(4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONATO)METALATE COMPLEXES AT THE AIR-WATER-INTERFACE

被引：33

作者：

GUPTA, SK

TAYLOR, DM

DYNAROWICZ, P

BARLOW, E

WAINWRIGHT, CEA

UNDERHILL, AE

机构：

[1] UNIV WALES,INST MOLEC & BIOMOLEC ELECTR,BANGOR LL57 1UT,GWYNEDD,WALES

[2] JAGIELLONIAN UNIV,FAC CHEM,DEPT GEN CHEM,PL-31007 KRAKOW,POLAND

来源：

LANGMUIR | 1992年 / 8卷 / 12期

关键词：

D O I：

10.1021/la00048a035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that the behavior of divalent salts of bis(didodecyldimethylammonium) bis(4,5-dimercapto-1,3-dithiole-2-thionato)metalate at the air-water interface is complex. The pressure-area isotherms are shown to depend on a number of experimental variables including subphase temperature, spreading time, and compression rate. From a combination of surface pressure and surface potential isotherms, conditions are identified which lead to stable and reproducible monolayer behavior as well as to the deposition of good quality Langmuir-Blodgett films by the vertical dipping method.

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页码：3057 / 3062

页数：6

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