A STEREOCONTROLLED SYNTHESIS OF (4AS,8AR)-(+)-7,7-ETHYLENEDIOXY-4,4,8A-TRIMETHYLOCTAHYDRO-2(1H)-NAPHTHALENONE

被引：1

作者：

KATO, M

WATANABE, M

MASUDA, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 08期

关键词：

D O I：

10.1246/bcsj.65.2071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stereocontrolled synthesis of (4aS,8aR)-(+)-7,7-ethylenedioxy-4,4,8a-trimethyloctahydro-2(1H)-naphthalenone, which will act as a versatile building block for the asymmetric synthesis of natural products possessing a trans-1, 1,4a-trimethyldecalin unit, was accomplished starting with (1 R,4S,5R)-(+)4,6,6-trimethyl-4-vinylbicyclo[3. 1. l]-heptan-2-one, readily accessible from (+)-nopinone.

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页码：2071 / 2075

页数：5

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