SYNTHESIS OF 4-((BENZYLOXYMETHYL)(TERT-BUTYL)METHYLSILYLOXY)-1,2,3-PENTATRIENE VIA BROOK REARRANGEMENT

被引：11

作者：

BIENZ, S

ENEV, V

HUBER, P

机构：

[1] Organisch-chemisches Institut der Universität Zürich, CH-8057 Zürich

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 08期

关键词：

D O I：

10.1016/0040-4039(94)88012-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 1-lithium-3-tetrahydropyranyloxy-1-propyne with {(benzyloxymethyl)-(tert.-butyl)methylsilyl} methyl ketone gave rise to the corresponding alpha-silylated propargylic alcoholate anion, which led in a succession of Brook rearrangement and 1,4-elimination to the title compound in good yield.

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页码：1161 / 1162

页数：2

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