SYNTHESIS OF 3-(1-ADAMANTYL)PYRAZOLE AND 3,5-DI(1-ADAMANTYL)PYRAZOLE IN A MICROWAVE-OVEN

被引：19

作者：

FORFAR, I ^{[1
]}

CABILDO, P ^{[1
]}

CLARAMUNT, RM ^{[1
]}

ELGUERO, J ^{[1
]}

机构：

[1] CSIC, E-28040 MADRID, SPAIN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2079

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An extraordinary inversion of the regioselectivity in the reaction of C-adamantylation of pyrazoles by 1-bromoadamantane was observed when the autoclave vessel was replaced by a microwave oven. In these last conditions mono and disubstituted 3(5)-(1-adamantyl) pyrazoles were obtained.

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页码：2079 / 2080

页数：2

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