THERMODYNAMICS OF THE ELECTRON AND THE PROTON

被引:427
作者
BARTMESS, JE
机构
[1] Department of Chemistry, University of Tennessee, Knoxville
关键词
D O I
10.1021/j100076a029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The currently accepted conventions for the thermodynamics of the electron do not follow the proper statistical mechanics equations. The correct values are here obtained from numerical solution of the Fermi-Dirac statistical mechanics equations, yielding an entropy at 298.15 K of 22.734 J/mol.K (5.434 cal/mol.K) and an integrated heat capacity at the same temperature of 3.145 kJ/mol.K (0.752 kcal/mol). The effect that this would have, based on the current thermochemical conventions, on the thermodynamics of the proton, and of all other gaseous ions, is noted.
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页码:6420 / 6424
页数:5
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