OXIDATION OF HYDRAZINE DERIVATIVES .I. OXIDATION OF PHENYLHYDRAZINE WITH LEAD TETRA-ACETATE

被引：47

作者：

AYLWARD, JB

机构：

[1] Department of Chemistry, University of Malaya, Kuala Lumpur

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 12期

关键词：

D O I：

10.1039/j39690001663

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of phenylhydrazine with lead tetra-acetate in the solvents benzene, chlorobenzene, nitrobenzene, and dichloromethane has been investigated. At low temperatures in dichloromethane the benzenediazonium ion was formed. At room temperature, benzene, azobenzene, biphenyl, and, where aromatic solvents were used, biaryls, were isolated and identified. The formation of these products can be explained in terms of the formation of phenyldi-imide and its subsequent homolytic and heterolytic breakdown.

引用

页码：1663 / &

共 36 条

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