REACTIONS OF RADICAL ANIONS .7. DISPROPORTIONATION OF RADICAL ANION OF ACENAPHTHENEQUINONE

被引：14

作者：

EVANS, AG

EVANS, JC

GODDEN, EH

机构：

[1] Chemistry Department, University College, Cardiff, Cathays Park

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 05期

关键词：

D O I：

10.1039/j29690000546

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An e.s.r. study of the disproportionation of the radical-anion of acenaphthenequinone, 2(AQ·-M+) ⇌ ab (AQ2-2M+) + AQ gives the results at -10° for Li+, Na+, K+, Rb+, and Cs+: K1. 38,200,1110, 86.5, 35.9, and 10,800; ΔG1a, -5.8, -4.0, -2.3, -2.0, and -4.7 kcal, mole-1; ΔH1a°, -13.8, -5.8, -7.3, -6.9. and -6.7 kcal, mole -1; ΔS1a,°, -30.5, -6.9, -19.0, -18.5, and -7.6 cal. deg.-1 mole-1 respectively.

引用

页码：546 / &

共 15 条

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