APPROACH TO ENOLONIUM EQUIVALENTS - APPLICATION TO A TOTAL SYNTHESIS OF (+/-)-PYRENOPHORIN

被引：70

作者：

TROST, BM

GOWLAND, FW

机构：

[1] Samuel M. McElvain Laboratories of Organic Chemistry, Department of Chemistry, University of Wisconsin-Madison, Madison

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 19期

关键词：

D O I：

10.1021/jo01333a052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkoxy-bearing allylic acetates can serve as substrates for palladium(0) catalysts under special conditions and thus constitute the equivalent of an enolonium and a vinylogous enolonium ion, a feature that has led to a formal synthesis of pyrenophorin and a synthesis of a fragment of zealeranone. Copyright © 1979, American Chemical Society. All rights reserved.

引用

页码：3448 / 3450

页数：3

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