BETA-PHOSPHORYLATED CYCLIC NITROXIDES .2. SYNTHESIS OF PYRROLIDIN-2-YL AND PIPERIDIN-2-YL PHOSPHONATES AND THE CORRESPONDING STABLE NITROXIDES

被引：34

作者：

LEMOIGNE, F ^{[1
]}

MERCIER, A ^{[1
]}

TORDO, P ^{[1
]}

机构：

[1] UNIV PROVENCE,FAC ST JEROME,CNRS,STRUCT & REACT ESPECES PARAMAGNET LAB,UA 1412,F-13397 MARSEILLE 13,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 31期

关键词：

BETA-PHOSPHORYLATED NITROXIDES; ALPHA-AMINOPHOSPHONATES; INTRAMOLECULAR AMINOMERCURATION; ESR;

D O I：

10.1016/S0040-4039(00)79391-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkenyl alpha-aminophosphonates are cyclized by intramolecular aminomercuration to give pyrrolidin- and piperidin-2-yl phosphonates which lead, after oxidation with m-CPBA, to the corresponding stable beta-phosphorylated nitroxides.

引用

页码：3841 / 3844

页数：4

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