EFFECT OF MOLECULAR-WEIGHT ON GLASS-TRANSITION TEMPERATURES (COMPOSITIONAL VARIATION OF GLASS-TRANSITION TEMPERATURES-3)

被引：27

作者：

COUCHMAN, PR

机构：

[1] Department of Mechanics and Materials Science, Rutgers University, New Brunswick

来源：

JOURNAL OF APPLIED PHYSICS | 1979年 / 50卷 / 10期

关键词：

D O I：

10.1063/1.325792

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A predictive equation for the influence of chain ends on glass-transition temperatures is derived from a thermodynamic theory for the compositional variation of Tg. This relation is found to give excellent agreement with results for the effect in polystyrene, and produces a convenient and accurate first approximation. Secondary approximations to the principal equation are formally identical to the Ueberreiter-Kanig and Fox-Flory equations for the variation of Tg with molecular weight.

引用

页码：6043 / 6046

页数：4

共 18 条

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[10] FRIED J, UNPUBLISHED

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