ULTRASONICALLY DISPERSED POTASSIUM IN ORGANIC-SYNTHESIS - WATER-ACCELERATION IN REDUCTIVE C-S BOND-CLEAVAGE REACTIONS

被引：17

作者：

CHOU, TS ^{[1
]}

HUNG, SH ^{[1
]}

PENG, ML ^{[1
]}

LEE, SJ ^{[1
]}

机构：

[1] ACAD SINICA,INST CHEM,TAIPEI 115,TAIWAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 29期

关键词：

D O I：

10.1016/0040-4039(91)80830-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The slow addition of a pre-measured amount of water in THF can greatly enhance the UDP induced C-S bond cleavage reactions of cyclic sulfones. This reaction can be used in the synthesis of open chain sulfones with gamma-, delta- or epsilon-deuteration.

引用

页码：3551 / 3554

页数：4

共 10 条

[1] CHEMOSELECTIVE REACTIONS OF ULTRASONICALLY DISPERSED POTASSIUM WITH SOME BROMINATED HYDROTHIOPHENE S,S-DIOXIDES [J].