DIRECT INJECTION SUPERSONIC CLUSTER BEAM SOURCE FOR FT-ICR STUDIES OF CLUSTERS

被引:203
作者
MARUYAMA, S
ANDERSON, LR
SMALLEY, RE
机构
[1] RICE UNIV,DEPT CHEM,HOUSTON,TX 77251
[2] RICE UNIV,DEPT PHYS,HOUSTON,TX 77251
关键词
D O I
10.1063/1.1141536
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A miniaturized pulsed supersonic beam source has been developed using laser vaporization of a computer-controlled target disk, producing intense beams of cluster ions with excellent repeatability and control. Due to its small size and narrow pulse width, the entire source is adequately pumped by a single 170 l /s turbopump. The resultant vacuum quality permits this source to be attached to a Fourier transform ion cyclotron resonance apparatus (FT-ICR) such that the supersonic cluster ion beam is directly injected. The result is a powerful but simple FT-ICR instrument of wide applicability. The new source is suited as well for a variety of other uses such as molecular beam epitaxy.
引用
收藏
页码:3686 / 3693
页数:8
相关论文
共 39 条
[1]  
ABENATHY CR, 1990, APPL PHYS LETT, V56, P2654
[2]  
ALFORD JL, UNPUB
[3]   DISSOCIATIVE CHEMISORPTION OF H-2 ON NIOBIUM CLUSTER IONS - A SUPERSONIC CLUSTER BEAM FT-ICR EXPERIMENT [J].
ALFORD, JM ;
WEISS, FD ;
LAAKSONEN, RT ;
SMALLEY, RE .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (19) :4480-4482
[4]   METAL CLUSTER ION-CYCLOTRON RESONANCE - COMBINING SUPERSONIC METAL CLUSTER BEAM TECHNOLOGY WITH FT-ICR [J].
ALFORD, JM ;
WILLIAMS, PE ;
TREVOR, DJ ;
SMALLEY, RE .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1986, 72 (1-2) :33-51
[5]  
ALFORD JM, 1989, MATER RES SOC S P, V131, P3
[6]  
ANDERSON LR, IN PRESS CHEM PHYS L
[7]   ELECTRONIC SPECTROSCOPY OF SMALL TRYPTOPHAN PEPTIDES IN SUPERSONIC MOLECULAR-BEAMS [J].
CABLE, JR ;
TUBERGEN, MJ ;
LEVY, DH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (22) :7349-7355
[8]   ULTRAVIOLET PHOTOELECTRON-SPECTRA OF MASS-SELECTED COPPER CLUSTERS - EVOLUTION OF THE 3D BAND [J].
CHESHNOVSKY, O ;
TAYLOR, KJ ;
CONCEICAO, J ;
SMALLEY, RE .
PHYSICAL REVIEW LETTERS, 1990, 64 (15) :1785-1788
[9]   A TIME-OF-FLIGHT MASS-SPECTROMETER FOR LARGE MOLECULAR CLUSTERS PRODUCED IN SUPERSONIC EXPANSIONS [J].
CONOVER, CWS ;
TWU, YJ ;
YANG, YA ;
BLOOMFIELD, LA .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1989, 60 (06) :1065-1070
[10]   PROBING C-60 [J].
CURL, RF ;
SMALLEY, RE .
SCIENCE, 1988, 242 (4881) :1017-1022