SYNTHESIS AND X-RAY STRUCTURE OF A CHROMIUM(III)-RHODIUM(III) HETEROMETALLIC HYDROLYTIC DIMER - [(H2O)4RH(MU-OH)2CR(OH2)4](ME3C6H2SO3)4.4H2O

被引：17

作者：

CRIMP, SJ ^{[1
]}

FALLON, GD ^{[1
]}

SPICCIA, L ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterometallic chromium(III)-rhodium(III) oligomers are formed on addition of Cr3+ to alkaline Rh3+ solutions and can be separated by ion-exchange chromatography; solution characterization studies have established the existence of a bis(mu-hydroxo) dimer, [(H2O)4Rh(mu-OH)2Cr(OH2)4]4+, whose structure has been confirmed by X-ray diffraction studies on [(H2O)4Rh(mu-OH)2Cr(OH2)4](Me3C6H2SO3)4.4H2O.

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页码：197 / 198

页数：2

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