ENZYME-LIKE ENANTIOSELECTIVE CATALYSIS OVER CHIRAL MOLECULAR FOOTPRINT CAVITIES ON A SILICA (ALUMINA) GEL SURFACE

被引：44

作者：

MORIHARA, K

KUROKAWA, M

KAMATA, Y

SHIMADA, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000358

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral catalytic cavities were imprinted on a silica gel surface using a chiral template, N-benzoyl-(N(alpha)-benzyloxycarbonyl)-L-alanineamide, by an imprinting procedure; these cavities display enantioselective catalysis in 2,4-dinitrophenolysis of the corresponding substrate, benzoic N-benzyloxycarbonyl-L-alanine anhydride.

引用

页码：358 / 360

页数：3

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[2]

BERNHARD SA, 1958, P INT S ENZYME CHEM, P124

[3]

Fischer E., 1894, BER DEUT CHEM GES, V27, P2985

[4] A QUANTITATIVE ANALYSIS OF BINDING OF N-ACYL DERIVATIVES OF ALPHA-AMINOAMIDES BY ALPHA-CHYMOTRYPSIN [J].