ORTHO ENHANCEMENT IN THE OZONE-MEDIATED NITRATION OF SOME AROMATIC CARBONYL-COMPOUNDS WITH NITROGEN-DIOXIDE

被引：13

作者：

SUZUKI, H

MURASHIMA, T

TATSUMI, A

KOZAI, I

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl aryl ketones react smoothly with nitrogen dioxide at low temperatures in the presence of ozone to give a mixture of ortho and meta nitration products (o/m = 1.1-3.8/1.0), the former becoming predominant with the increasing size of alkyl moiety.

引用

页码：1421 / 1424

页数：4

共 8 条

[1] The salt forming characteristic of doubly- and singly-linked elements of the oxygen group Part II Nitration of benzaldehyde and aceto-phenone in sulphuric acid solution [J].

Baker, JW ;

Moffit, WG .

JOURNAL OF THE CHEMICAL SOCIETY, 1931, :314-318

[2]

KSUZUKI H, 1991, CHEMLETT, P817

[3] ELECTROPHILIC SUBSTITUTION .4. KINETICS OF NITRATION OF ACETOPHENONE BENZAMIDE BENZOIC ACID AND NN-DIMETHYLANILINE N-OXIDE IN AQUEOUS SULPHURIC ACID [J].

MOODIE, RB ;

PENTON, JR ;

SCHOFIEL.K .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1969, (05) :578-&

[4] NITRATION AND OXIDATION OF SUBSTITUTED BENZALDEHYDES IN SOLUTIONS OF DINITROGEN PENTAOXIDE OR NITRONIUM TRIFLUOROMETHANESULFONATE IN NITRIC-ACID [J].

MOODIE, RB ;

WILLMER, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (02) :229-233

[5] ORTHO-SELECTIVE NITRATION OF ACETANILIDES WITH NITROGEN-DIOXIDE IN THE PRESENCE OF OZONE [J].

SUZUKI, H ;

ISHIBASHI, T ;

MURASHIMA, T ;

TSUKAMOTO, K .

TETRAHEDRON LETTERS, 1991, 32 (45) :6591-6594

[6]

SUZUKI H, 1991, CHEM COMMUN, P1049

[7]

SUZUKI H, 1993, IN PRESS J CHEM SOC

[8] THE NITRATE RADICAL - PHYSICS, CHEMISTRY, AND THE ATMOSPHERE [J].

WAYNE, RP ;

BARNES, I ;

BIGGS, P ;

BURROWS, JP ;

CANOSAMAS, CE ;

HJORTH, J ;

LEBRAS, G ;

MOORTGAT, GK ;

PERNER, D ;

POULET, G ;

RESTELLI, G ;

SIDEBOTTOM, H .

ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1991, 25 (01) :1-203

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