EFFICIENT OXYGENATION OF ALKENE THROUGH REDUCTIVE QUENCHING OF EXCITED SB(V)TETRAPHENYLPORPHYRIN BY TRIPHENYLPHOSPHINE

被引：23

作者：

OKAMOTO, T ^{[1
]}

TAKAGI, S ^{[1
]}

SHIRAGAMI, T ^{[1
]}

INOUE, H ^{[1
]}

机构：

[1] TOKYO METROPOLITAN UNIV, FAC TECHNOL, DEPT IND CHEM, 1-1 MINAMI OHSAWA, HACHIOJI, TOKYO 19203, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 04期

关键词：

D O I：

10.1246/cl.1993.687

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel efficient oxygenation route of cyclohexene into 2-cyclohexen-1-one (PHI =0.14) upon visible light irradiation to tetraphenylporphyrinatoantimony(V) through reductive quenching of the excited triplet porphyrins by triphenylphosphine in aqueous acetonitrile has been found.

引用

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页码：687 / 690

页数：4

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