SYNTHESIS OF (HEXAFLUORO-TERT-BUTYL)AMINE AND MOLYBDENUM(VI) (HEXAFLUORO-TERT-BUTYL)IMIDO COMPLEXES

被引：4

作者：

BUCHMEISER, M ^{[1
]}

SCHROCK, RR ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 13期

关键词：

D O I：

10.1021/ic00117a027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(CF3)(2)MeCNH(3)]Cl-+(-) was synthesized from (CF3)(2)C=NH in an overall yield of 90-95%. Attempts to prepare a variety of hexafluoro-tert-butylamido complexes of molybdenum, including metathesis catalysts analogous to compounds of the type Mo(CHR)(NAr)(OR')(2) (where Ar = 2,6-i-Pr2C6H3), were unsuccessful.

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页码：3553 / 3554

页数：2

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