KINETICS OF INHIBITED OXIDATION OF LIPIDS IN THE PRESENCE OF 1-OCTADECANOL AND 1-PALMITOYLGLYCEROL

被引:20
作者
KORTENSKA, VD [1 ]
YANISHLIEVA, NV [1 ]
ROGINSKII, VA [1 ]
机构
[1] BULGARIAN ACAD SCI,CTR PHYTOCHEM,INST ORGAN CHEM,BL 9,BU-1040 SOFIA,BULGARIA
关键词
1-OCTADECANOL; 1-PALMITOYLGLYCEROL; INHIBITED OXIDATION; KINETICS; LIPIDS;
D O I
10.1007/BF02660609
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The kinetics of initiated oxidation of sunflower oil methyl esters at 50-degrees-C in the presence of the phenolic inhibitor p-methoxyphenol are investigated. It is established that addition of 0.1 M 1-octadecanol and of 0.1 M 1-palmitoylglycerol leads to a 1.5- or 2.3-fold decrease of the rate constant of chain termination on the inhibitor, which proves the blocking of its effect due to the formation of a complex based on a hydrogen bond. The stronger effect of 1-palmitoylglycerol is explained by the presence of two hydroxyl groups in its molecule.
引用
收藏
页码:888 / 890
页数:3
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