SYNTHESIS AND CHARACTERIZATION OF POLY(DICHLOROPHENYLENE OXIDE)S THROUGH SOLID-STATE THERMAL-DECOMPOSITION OF BIS(PYRIDINE)BIS(TRICHLOROPHENOXO)COPPER(II) COMPLEXES

被引：22

作者：

BASTURKMEN, M ^{[1
]}

KISAKUREK, D ^{[1
]}

机构：

[1] MIDDLE E TECH UNIV,DEPT CHEM,ANKARA,TURKEY

来源：

POLYMER | 1993年 / 34卷 / 03期

关键词：

POLY(DICHLOROPHENYLENE OXIDE); SOLID STATE THERMAL POLYMERIZATION; BIS(PYRIDINE)BIS(TRICHLOROPHENOXO)COPPER(II) COMPLEX; INTRINSIC VISCOSITY; H-1; NMR; C-13;

D O I：

10.1016/0032-3861(93)90561-N

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermal polymerization of bis(pyridine)bis(trichlorophenoxo)copper(II) was achieved in the solid state for the first time. The time and temperature effect on polymer molecular weight, percentage yield and the structure of polymer was first studied, at constant temperature and then for constant decomposition time. Polymers were characterized by i.r., H-1 n.m.r. and C-13 n.m.r. The molecular weights of the polymers were obtained by viscometric measurements at 30-degrees-C in toluene and glass transition temperatures were obtained by d.s.c.

引用

页码：625 / 629

页数：5

共 14 条

[1]

BLANCHARD HS, 1962, J POLYM SCI A2, V58, P469, DOI 10.1002/pol.1962.1205816626

[2] CHEMISTRY OF PHENOXO COMPLEXES .1. MECHANISM OF DECOMPOSITION OF PHENOXOCOPPER(II) COMPLEXES [J].