MOTION IN SOLID ORGANOTIN(IV) COORDINATION POLYMERS - A 2-DIMENSIONAL EXCHANGE MAGIC ANGLE SPINNING C-13 NMR-STUDY

被引：19

作者：

APPERLEY, DC

DAVIES, NA

HARRIS, RK

ELLER, S

SCHWARZ, P

FISCHER, RD

机构：

[1] UNIV DURHAM,IND RES LAB,SOUTH RD,DURHAM DH1 3LE,ENGLAND

[2] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

[3] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,W-2000 HAMBURG 13,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 10期

关键词：

D O I：

10.1039/c39920000740

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid-state C-13 CP MAS NMR studies of compounds [(Me3Sn)4M(CN)6]infinity with M = Fe, Ru and Os, using variable temperature, show that the trigonal bipyramidal arrangements at Sn are undergoing internal rotation about the N-Sn-N axes with lifetimes of the order of 0.5 s at moderately lowered temperature.

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页码：740 / 741

页数：2

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