NANOPOROUS TIN(IV) SULFIDES - MODE OF FORMATION

被引：92

作者：

JIANG, T ^{[1
]}

OZIN, GA ^{[1
]}

BEDARD, RL ^{[1
]}

机构：

[1] UOP TARRYTOWN TECH CTR,TARRYTOWN,NY 10591

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 11期

关键词：

D O I：

10.1002/adma.19940061114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous R-SnS-n materials, e.g. (Et4N)2Sn3S7, have recently been synthesized and characterized. The crystal structures of two molecular tin(IV) sulfide species that are thought to be important in the formation of these materials are reported. Both contain the dimer (Sn2S6)4-, which can be combined (see Figure) to form the Sn3S4 broken-cube clusters that constitute the open framework of R-SnS-1.

引用

页码：860 / 865

页数：6

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