POLYSILYL GROUP ISOMERIZATION VIA MIGRATIONS IN RHODIUM AND IRIDIUM DERIVATIVES (ME(3)P)(3)MSI(SIME(3))(3)

被引：52

作者：

MITCHELL, GP

TILLEY, TD

YAP, GPA

RHEINGOLD, AL

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] UNIV DELAWARE,DEPT CHEM & BIOCHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1021/om00012a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (Me(3)P)(3)RhCl with (THF)(3)LiSi(SiMe(3))(3) generates the thermally unstable complex (Me(3)P)(3)RhSiMe(2)SiMe(SiMe(3))(2) (1), probably via a series of 1,2- and 1,3-migrations. The analogous iridium reaction results in a similar rearrangement to give the iridacycle (Me(3)P)(3)(H)IrSiMe(2)SiMe(SiMe(3))SiMes(2)CH(2) as a mixture of diastereomers (2a,b), which is catalytically converted to an, equilibrium mixture by hydrogen.

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页码：5472 / 5474

页数：3

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