NITROSATION-OXIDATIVE RING CONTRACTION OF ALPHA-TOCOPHEROL BY REACTION WITH NITRIC-OXIDE UNDER AEROBIC CONDITIONS

被引：20

作者：

DISCHIA, M

机构：

[1] Department of Organic and Biological Chemistry, University of Naples, Naples, I-80134

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 48期

关键词：

D O I：

10.1016/0040-4039(95)01846-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Exposure of alpha-tocopherol (1) to nitric oxide (NO) in air-saturated cyclohexane leads to a complex mixture of products, one of which, relatively more polar, has been isolated and identified as the novel 2,3-dimethyl-4-acetyl-4-hydroxy-5-nitroso-2-cyclopentenone derivative 5.

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页码：8881 / 8884

页数：4

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