New ternary rare-earth transition-metal antimonides RE(3)MSb(5) (RE=La,Ce,Pr,Nd,Sm; M=Ti,Zr,Hf,Nb)

被引：45

作者：

Bollore, G ^{[1
]}

Ferguson, MJ ^{[1
]}

Hushagen, RW ^{[1
]}

Mar, A ^{[1
]}

机构：

[1] UNIV ALBERTA,DEPT CHEM,EDMONTON,AB T6G 2G2,CANADA

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 12期

关键词：

D O I：

10.1021/cm00060a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Arc-melting mixtures of the elements produced a new series of antimonides RE(3)MSb(5) (RE = La, Ce, Pr, Nd, Sm; M = Ti, Zr, Hf, Nb). The structure of La3TiSb5 was determined from single-crystal X-ray diffraction data. Nine-coordinate La atoms separate one-dimensional chains of Sb atoms and columns of face-sharing TiSb6 octahedra.

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页码：2229 / &

页数：4

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