REACTIVITY OF TRIOSMIUM AND TRIRUTHENIUM CARBON RADICALS TOWARD FLUOROBENZENE AND HEXAFLUOROBENZENE

被引：3

作者：

HADJBAGHERI, N ^{[1
]}

STRICKLAND, DS ^{[1
]}

WILSON, SR ^{[1
]}

SHAPLEY, JR ^{[1
]}

机构：

[1] UNIV ILLINOIS,SCH CHEM SCI,URBANA,IL 61801

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80008-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The radicals H3M3(CO)9(mu-3-C.), generated by photolyzing a mixture of Re2(CO)10 and H3M3-(CO)9(mu-3-CBr) (M = Ru, Os), are found to add to C6F6 and C6H5F. With C6F6 the major products are the pentafluorophenyl derivatives H3M3(CO)9(mu-3-CC6F5), whereas with C6H5F thhe major products are the phenyl derivatives H3M3(CO)9(mu-3-CC6H5).

引用

页码：231 / 239

页数：9

共 16 条

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