2-ELECTRON REDUCTION OF 1,1,4,4-TETRAPHENYLBUTADIENE BY SODIUM OR POTASSIUM TO BUT-2-ENE-1,4-DIYL SALTS OF DIFFERENT STRUCTURE

被引：26

作者：

BOCK, H

NATHER, C

RUPPERT, K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 10期

关键词：

D O I：

10.1039/c39920000765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of 1,1,4,4-tetraphenylbutadiene in ether solution at sodium or potassium metal mirrors proceeds via C=C double bond shifts and yields either a monomeric contact ion triple unit {tetraphenylbutadiene2--[Na+(dimethoxyethane)2]2}1, or a polymeric contact ion aggregate, [tetraphenylbutadiene2-(K+ diethyl ether)2]infinity.

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页码：765 / 766

页数：2

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