PREPARATION OF A 4-MEMBERED INDIUM-PHOSPHORUS RING WITH A HYDROGEN-ATOM BOUND TO PHOSPHORUS - CRYSTAL-STRUCTURE OF [(ME3SICH2)2-INPH-TERT-BU]2

被引：13

作者：

DEMBOWSKI, U

NOLTEMEYER, M

ROCKENSUSS, W

STUKE, M

ROESKY, HW

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

[2] MAX PLANCK INST BIOPHYS CHEM,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 12期

关键词：

INDIUM-PHOSPHORUS 4-MEMBERED RING; PHOSPHIDE; PHOSPHORUS-INDIUM BOND; PHOSPHORUS-HYDROGEN BOND;

D O I：

10.1002/cber.19901231217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of tBuPH2 (1) with (Me3SiCH2)3In (2) in the presence of Ag+ ions leads to [(Me3SiCH2)2InPHtBu]2 (3). According to an X-ray structure analysis, 3 forms a four-membered planar P2In2 ring with alternating P-In bonds and crystallizes in the monoclinic space group C2/c.

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页码：2335 / 2336

页数：2

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