MICROWAVE-SPECTRUM OF CH3OD

被引：20

作者：

KAUSHIK, VK ^{[1
]}

TAKAGI, K ^{[1
]}

MATSUMURA, C ^{[1
]}

机构：

[1] NATL CHEM LAB IND,SHIBUYA KU,TOKYO 151,JAPAN

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1980年 / 82卷 / 02期

关键词：

Excited states - Microwave spectroscopy - Vibration analysis;

D O I：

10.1016/0022-2852(80)90125-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The microwave spectrum of CH3OD has been observed in the frequency region between 14 and 92 GHz. All the ground-state transitions with J ≤ 8 and J = 2 → 1, a-type transitions in the excited torsional states (ν = 1 and ν = 2) have been observed. The spectrum has been analyzed and rotational constants, torsional constants, torsion-vibration-rotation interaction constants, and centrifugal distortion constants have been evaluated. The Stark effect measurements have been made and the dipole moment components have been determined as μa = 0.833 ± 0.008 D and μb = 1.488 ± 0.015 D. Copyright © 1980 by Academic Press, Inc.

引用

页码：418 / 426

页数：9

共 25 条

[1] EXPERIMENTAL EVIDENCE OF RESTRICTED ROTATION IN CH3-C=C-CF3 [J].