A STRUCTURAL MODEL FOR VANADYL HISTIDINE INTERACTIONS - STRUCTURE DETERMINATION OF [VO(1-VINYLIMIDAZOLE)4CL]CL BY A COMBINATION OF X-RAY CRYSTALLOGRAPHY AND X-RAY ABSORPTION-SPECTROSCOPY

被引：30

作者：

CALVIOU, LJ

ARBER, JM

COLLISON, D

GARNER, CD

CLEGG, W

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000654

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[VO(1-vinylimidazole)4Cl]Cl is prepared and spectroscopically characterized and structural information obtained from vanadium K-edge EXAFS used to solve a disorder problem encountered in the refinement of the crystal structure; oxovanadium(IV) bound to imidazole groups has relevance to the possible biochemical functions of vanadium.

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收藏

页码：654 / 656

页数：3

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