POLYFUNCTIONAL CARBOSILANES AND ORGANOSILICON COMPOUNDS - SYNTHESIS VIA GRIGNARD REACTIONS

被引：31

作者：

BRONDANI, DJ ^{[1
]}

CORRIU, RJP ^{[1
]}

ELAYOUBI, S ^{[1
]}

MOREAU, JJE ^{[1
]}

MAN, MWC ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,DEPT CHIM ORGAN FINE,RP,CNRS,UNITE MIXTE 44,F-34095 MONTPELLIER 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期

关键词：

TRIALKOXYSILYLATION REACTION; (TRIETHOXYSILYL)METHYL GRIGNARD; CARBOSILANES; CROSS-COUPLING REACTION;

D O I：

10.1016/S0040-4039(00)60358-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The THF solutions of (triethoxysilyl)methyl magnesium chloride are stable at low temperature. At 20-degrees-C, the Grignard reagent underwent intermolecular condensation, providing a simple synthesis of cyclic carbosilanes derivatives. The cross-coupling reaction with organic halides also afforded a facile route to a variety of trifunctional organosilicon compounds.

引用

页码：2111 / 2114

页数：4

共 30 条

[1] POLYMERIZATION OF PRIMARY SILANES TO LINEAR POLYSILANES CATALYZED BY TITANOCENE DERIVATIVES
AITKEN, C
HARROD, JF
SAMUEL, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 279 (1-2) : C11 - C13
[2] SILYLATION OF ORGANIC HALIDES . A NEW METHOD OF FORMING CARBON-SILICON BOND
BENKESER, RA
GAUL, JM
SMITH, WE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (13) : 3666 - &
[3] CHEMISTRY OF TRICHLOROSILANE-TERT AMINE COMBINATIONS
BENKESER, RA
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1971, 4 (03) : 94 - &
[4] BRINKER CJ, 1992, SOL GEL SCI
[5] BRONDANI DJ, IN PRESS
[6] ADDITION OF GRIGNARD REAGENTS TO VINYLSILANES
BUELL, GR
CORRIU, R
GUERIN, C
SPIALTER, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (25) : 7424 - &
[7] Corriu R. J. P., 1991, SILICON HETEROATOM B, P1
[8] NEW MIXED ORGANIC INORGANIC POLYMERS - HYDROLYSIS AND POLYCONDENSATION OF BIS(TRIMETHOXYSILYL)ORGANOMETALLIC PRECURSORS
CORRIU, RJP
MOREAU, JJE
THEPOT, P
MAN, MWC
[J]. CHEMISTRY OF MATERIALS, 1992, 4 (06) : 1217 - 1224
[9] FURTHER-STUDIES ON REACTIONS OF ORGANIC HALIDES WITH DISILANES CATALYZED BY TRANSITION-METAL COMPLEXES
EABORN, C
GRIFFITHS, RW
PIDCOCK, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 225 (01) : 331 - 341
[10] FORMATION OF ORGANO-SILICON COMPOUNDS .100. ISOLATION OF HIGHER MOLECULAR CARBOSILANES FROM THE PYROLYSIS PRODUCTS OF TETRAMETHYLSILANE
FRITZ, G
WORNS, KP
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 512 (05): : 103 - 125

← 1 2 3 →