NEW DECONTAMINANTS - OXIDATIVE ELIMINATION OF AN YPERITE ANALOG, 2-PHENYL-2'-CHLORODIETHYLSULFIDE, USING POTASSIUM MONOPERSULFATE

被引：18

作者：

LEBLANC, A

FOSSET, L

MAGNAUD, G

DELMAS, G

DESGRANGES, M

SENTENACROUMANOU, H

LION, C

CHARVY, C

MOHRI, A

机构：

[1] MINIST DEF NATL,DRET,F-00460 ARMEES,FRANCE

[2] UNIV PARIS 07,INST TOPOL & DYNAM SYST,F-75221 PARIS 05,FRANCE

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 79卷 / 1-4期

关键词：

DECONTAMINATION; POTASSIUM MONOPERSULFATE; YPERITE;

D O I：

10.1080/10426509308034407

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of potassium monopersulfate (CUROX or OXONE) with 2-phenyl 2'-chloro diethylsulfide PhCH2CH2SCH2CH2Cl goes to completion in a very short time. The intermediate chlorinated sulfone PhCH2CH2SO2CH2CH2Cl leads the phenethylvinylsulfone PhCH2CHSO2CH=CH2 by HCl elimination.

引用

页码：141 / 145

页数：5

共 22 条

[1] KINETICS OF HYDROLYSIS AND DISPLACEMENT REACTIONS OF BETA,BETA-'-DICHLORODIETHYL SULFIDE (MUSTARD GAS) AND OF BETA-CHLORO-BETA-'-HYDROXYDIETHYL SULFIDE (MUSTARD CHLOROHYDRIN) [J].