CONDUCTANCE OF SOLUTIONS OF CESIUM IN LIQUID AMMONIA

被引：13

作者：

DEWALD, RR

机构：

[1] Department of Chemistry, Tufts University, Medford

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 08期

关键词：

D O I：

10.1021/j100842a026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conductivity of cesium-ammonia solutions at -33.9, -45.0, and -65.0° has been measured over the concentration range of 0.425 to 1.23 × 10-4 M. The method of Shedlovsky was used to evaluate the data in the dilute range. Values of 1142, 954, and 672 for the apparent limiting equivalent conductance, and 4.87 × 10-3, 3.30 × 10-3, and 2.19 × 10-3 for the ion-pairing dissociation constants at -33.9, -45.0, and -65.0°, respectively, were determined. The results are compared with data reported for other metal-ammonia solutions.

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页码：2615 / &

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