NEW CHROMIUM CHALCOGENIDES PREPARED AT HIGH PRESSURE AND CRYSTAL GROWTH OF CHROMIUM SESQUISULFIDE

被引：38

作者：

SLEIGHT, AW

BITHER, TA

机构：

[1] Central Research Department, Experimental Station, du Pont de Nemours and Company, Wilmington, Delaware

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/ic50073a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new chromium chalcogenides Cr5S8, Cr5Se8, and Cr5S4.3Se32 have been prepared at pressures of 65-89 kbars. These phases have higher chalcogen-to-chromium ratios than have previously been reported in these systems. It is shown that they are isostructural with the known V5S8 and V5Se8 compounds. Their magnetic and electrical properties are reported, as well as the electrical properties of rhombohedral Cr2S3, which has been obtained for the first time in single-crystal form. © 1969, American Chemical Society. All rights reserved.

引用

页码：566 / &

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