SUCCESSIVE 1,4-ADDITION AND 1,2-ADDITION OF ORGANOMETALLIC REAGENTS TO A CHIRAL BINAPHTHYL ESTER - ONE-STEP SYNTHESIS OF OPTICALLY-ACTIVE KETONES

被引：24

作者：

FUJI, K

TANAKA, K

MIZUCHI, M

HOSOI, S

机构：

[1] Institute for Chemical Research, Kyoto University, Uji, 611, Kyoto-fu

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 49期

关键词：

D O I：

10.1016/0040-4039(91)80497-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organometallic reagents undergo a 1,4-addition onto the chiral binaphthyl ester of alpha,beta-unsaturated carboxylic acid followed by the formal 1,2-addition to yield optically active ketones directly.

引用

页码：7277 / 7280

页数：4

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