FLUORINE-19 NMR ANALYSIS OF THE CONFIGURATION OF PHENYL SUBSTITUTED 2-FLUORO-2-PHENYLACETIC ACID-ESTERS

被引：3

作者：

BEGUIN, C ^{[1
]}

HAMMAN, S ^{[1
]}

KABORE, L ^{[1
]}

LAURENT, E ^{[1
]}

MARQUET, B ^{[1
]}

机构：

[1] UNIV LYON 1, CNRS, CHIM ORGAN LAB 3, F-69622 VILLEURBANNE, FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 55卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)80114-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The F-19 NMR chemical shifts (delta(F)) of the p-ZPhCHFCO2CHL1L2 esters of 2-fluoro-2-substituted aryl acetic acids have been measured. The delta(F) values of the two diastereoisomers of these esters are linearly related to the delta+ Brown-Okamoto substituent parameters for each term of the series studied. The configuration of such ester of arylacetic acid can be deduced from their delta(F) values when compared to those of esters derived from the non-substituted acid of known configuration.

引用

页码：131 / 136

页数：6

共 9 条

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