X-RAY CRYSTAL-STRUCTURE DETERMINATION OF 1,3-BIS(DIETHYLAMINO)-1,3-DIBENZYL-2,4-DIPHENYL-1-LAMBDA-5, 3-LAMBDA-5-DIPHOSPHETE

被引：1

作者：

FLUCK, E

BRAUN, R

MULLER, A

BOGGE, H

机构：

[1] MAX PLANCK GESELL,GMELIN INST ANORGAN CHEM,FRANKFURT,GERMANY

[2] UNIV BIELEFELD,FAK CHEM,W-4800 BIELEFELD,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 609卷 / 03期

关键词：

DIPHOSPHETE; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19926090319

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Benzylidene-diethylamino-benzylfluorophosphorane, 1, reacts with lithium bis(trimethylsilyl)amide to give the title compound 2 and 1-diethylamino-2,3-diphenylphosphirane, 3. Only one of the stereoisomers of 2 is formed in which the two benzyl groups are located on the same side of the planar four-membered ring. 2 crystallizes in the monoclinic space group P2(1)/n.

引用

页码：99 / 102

页数：4

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