ON THE FORMATION OF THE [RHH(SNCL3)5]3- COMPLEX ANION - DIRECT SN-119-NMR EVIDENCE FOR THE FACILE PROTONATION OF THE [RH(SNCL3)5]4- SPECIES EXTRACTED INTO CHLOROFORM

被引：5

作者：

HALL, I ^{[1
]}

KOCH, KR ^{[1
]}

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

来源：

POLYHEDRON | 1991年 / 10卷 / 14期

关键词：

D O I：

10.1016/S0277-5387(00)83789-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Rh(SnCl3)5]4- complex anion, extracted into chloroform containing a quaternary ammonium type liquid anion exchanger, is readily and reversibly protonated in the chloroform phase to yield the stereochemically rigid, [RhH(SnCl3)5]3- complex.

引用

页码：1721 / 1722

页数：2

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