ZIRCONIUM-MEDIATED DIASTEREOSELECTIVE COUPLING REACTIONS OF CHIRAL ALDIMINE - REMARKABLE TEMPERATURE-DEPENDENCE OF CHIRAL INDUCTION

被引：52

作者：

ITO, H ^{[1
]}

TAGUCHI, T ^{[1
]}

HANZAWA, Y ^{[1
]}

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 31期

关键词：

ZIRCONOCENE; ZIRCONAAZIRIDINE; CHIRAL ALDIMINE; TEMPERATURE EFFECT; AMINO ALCOHOL DERIVATIVES;

D O I：

10.1016/S0040-4039(00)60112-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zr-Mediated coupling reactions of aldehyde with chiral aldimine which is derived from benzaldehyde and (R)-phenylglycinol methyl ether showed a remarkable temperature effect on the sense of chiral induction to yield amino alcohol derivatives with high diastereoselectivities.

引用

页码：4469 / 4472

页数：4

共 17 条

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