PREPARATION AND MAGNETIC-PROPERTIES OF MONODISPERSED ZN FERRITES OF SUBMICROMETRIC SIZE

被引:15
作者
ANDRESVERGES, M [1 ]
DEJULIAN, C [1 ]
GONZALEZ, JM [1 ]
SERNA, CJ [1 ]
机构
[1] CSIC,INST CIENCIA MAT,E-28006 MADRID,SPAIN
关键词
D O I
10.1007/BF00354700
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mixed ferrite samples of the ZnxFe3-xO4 system have been prepared by the solution method aiming at the obtention of submicrometric monodispersed particles. The crystalline structure, chemical composition and morphology of the samples was studied by means of X-ray diffraction, electron microscopy and energy-dispersive X-ray spectroscopy. The results obtained in this characterization evidenced (for samples of a given nominal composition) the uniformity in shape and size of the particles and their chemical homogenity down to the particle level. Nevertheless, measurements of the specific magnetization of the samples suggest some degree of inhomogeneity in the intraparticle cationic distribution.
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收藏
页码:2962 / 2966
页数:5
相关论文
共 20 条
[1]   INFLUENCE OF CRYSTALLITE SIZE ON MAGNETIC PROPERTIES OF ACICULAR GAMMA-FE2O3 PARTICLES [J].
BERKOWIT.AE ;
SCHUELE, WJ ;
FLANDERS, PJ .
JOURNAL OF APPLIED PHYSICS, 1968, 39 (2P2) :1261-&
[2]  
BOWEN HK, 1986, SCI AM, V255, P147
[3]   NONCOLLINEAR SPIN ARRANGEMENT IN ULTRAFINE FERRIMAGNETIC CRYSTALLITES [J].
COEY, JMD .
PHYSICAL REVIEW LETTERS, 1971, 27 (17) :1140-+
[4]  
FARMER VC, 1974, INFRARED SPECTRA MIN, P183
[5]   PREPARATION OF FINE, HOLLOW, SPHERICAL NIFE2O4 POWDERS [J].
GADALLA, AM ;
YU, HF .
JOURNAL OF MATERIALS RESEARCH, 1990, 5 (12) :2923-2927
[6]  
GONZALEZCARRENO T, 1991, MATER CHEM PHYS, V27, P278
[7]   AGGREGATION AND MATRIX EFFECTS ON THE INFRARED-SPECTRUM OF MICROCRYSTALLINE POWDERS [J].
IGLESIAS, JE ;
OCANA, M ;
SERNA, CJ .
APPLIED SPECTROSCOPY, 1990, 44 (03) :418-426
[8]  
JOHNSON DW, 1984, ADV CERAM, V15, P27
[9]  
KIYAMA M, 1980, P ICF, V3, P11
[10]   UNIFORM COLLOIDAL BARIUM FERRITE PARTICLES [J].
MATIJEVIC, E .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1987, 117 (02) :593-595