LONG-CHAIN FATTY-ACID ESTERS OF SOME NORDITERPENOID ALKALOIDS

被引：25

作者：

BAI, YL

DESAI, HK

PELLETIER, SW

机构：

[1] UNIV GEORGIA,INST NAT PROD RES,ATHENS,GA 30602

[2] UNIV GEORGIA,DEPT CHEM,ATHENS,GA 30602

来源：

JOURNAL OF NATURAL PRODUCTS | 1994年 / 57卷 / 07期

关键词：

D O I：

10.1021/np50109a013

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Several C-8 long-chain fatty acid esters of aconitine-type norditerpenoid alkaloids namely, aconitine, delphinine, delphisine, falconerine-8-acetace, mesaconitine, and pseudaconitine bearing a C-8 acetyl group, have been prepared. Preparation was achieved by heating the alkaloids with the neat fatty acid under vacuum. All the compounds have been fully characterized by physical and spectroscopic data. Identification and characterization of reaction byproducts are also included.

引用

收藏

页码：963 / 970

页数：8

相关论文

共 14 条

[1] C-13 FOURIER-TRANSFORM NUCLEAR MAGNETIC-RESONANCE .8. ROLE OF STERIC AND ELECTRIC-FIELD EFFECTS IN FATTY-ACID SPECTRA [J].

BATCHELOR, JG ;

CUSHLEY, RJ ;

PRESTEGARD, JH .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (12) :1698-1705

[2]

Benn M., 1983, ALKALOIDS CHEM BIOL, V1, P153

[3] ARROW POISONS IN CHINA .2. ACONITUM-BOTANY, CHEMISTRY, AND PHARMACOLOGY [J].

BISSET, NG .

JOURNAL OF ETHNOPHARMACOLOGY, 1981, 4 (03) :247-336

[4] CENTRIFUGAL CHROMATOGRAPHY OF DITERPENOID ALKALOIDS - USE OF ALUMINUM-OXIDE CONTAINING 2 FLUORESCENT MATERIALS [J].

DESAI, HK ;

TRUMBUL, ER ;

PELLETIER, SW .

JOURNAL OF CHROMATOGRAPHY, 1986, 366 :439-444

[5] ISOLATION AND IDENTIFICATION OF 4 NORDITERPENOID ALKALOIDS FROM PROCESSED AND UNPROCESSED ROOT TUBERS OF ACONITUM-FEROX [J].

HANUMAN, JB ;

KATZ, A .

JOURNAL OF NATURAL PRODUCTS, 1993, 56 (06) :801-809

[6] C-13 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY IN THE ELUCIDATION OF STRUCTURES OF DITERPENOID ALKALOIDS [J].

JOSHI, BS ;

WUNDERLICH, JK ;

PELLETIER, SW .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (01) :99-103

[7]

KITAGAWA I, 1982, CHEM PHARM BULL, V30, P758

[8]

MAJIMA R, 1924, BER DTSCH CHEM GES B, V57, P1468

[9]

PELLETIER SW, 1990, PHYTOCHEMISTRY, V29, P3649

[10] THE PYRODELPHONINE CHROMOPHORE - CRYSTAL-STRUCTURES OF PYRODELPHININE AND DELPHININE [J].

PELLETIER, SW ;

FINERMOORE, J ;

DESAI, RC ;

MODY, NV ;

DESAI, HK .

JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (27) :5290-5297