ONE-POT SYNTHESIS OF SUBSTITUTED ALLYL-ALPHA-D-GLUCOPYRANOSIDES BY AN IN-SITU ANOMERIZATION PROTOCOL

被引：21

作者：

CHARETTE, AB

TURCOTTE, N

COTE, B

机构：

[1] Departement de Chimie, Universite de Montreal, Montreal, Quebec, C.P. 6128, Succ. A

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1994年 / 13卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1080/07328309408009203

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A new 3-step, 1-pot procedure for the stereoselective alpha-glycosylation of substituted allylic alcohols has been developed. The key step involves an in situ anomerization of the beta-glycoside, obtained by Schmidt's glycosylation method, upon treatment with TiCl4.

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页码：421 / 432

页数：12

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