NOVEL SYNTHESIS OF 3-HYDROXY-BETA-DAMASCONE, 3-HYDROXYDIHYDRO-BETA-DAMASCONE AND BETA-DAMASCENONE

被引：8

作者：

KITAHARA, T

TAKAGI, Y

MATSUI, M

机构：

[1] Institute of Physical and Chemical Researchf, 2-1 Hirosawa, Wako-shi, Saitama

来源：

AGRICULTURAL AND BIOLOGICAL CHEMISTRY | 1979年 / 43卷 / 11期

关键词：

D O I：

10.1080/00021369.1979.10863798

中图分类号：

S3 [农学（农艺学）];

学科分类号：

0901 ;

摘要：

Naturally occurring damascone analogues, 3-hydroxy-/?-damascone, 3-hydroxydihydro-/?- damascone and jft-damascenone, which are known as key substances for the flavor of rose oil and tobacco, were synthesized via Diels-Alder reaction of the reactive diene, l-methoxy-3- tr imethy 1 sily 1 oxy-buta diene. © 1979 Taylor & Francis Group, LLC.

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页码：2359 / 2363

页数：5

相关论文

共 24 条

[1] SYNTHESIS OF DELTA-DAMASCONE [TRANS-1-(2,6,6-TRIMETHYLCYCLOHEX-3-ENYL)BUT-2-EN-1-ONE] AND BETA-DAMASCENONE [TRANS-1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIENYL)BUT-2-EN-1-ONE] [J].

AYYAR, KS ;

COOKSON, RC ;

KAGI, DA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (17) :1727-1736

[2] LITHIUM TRI-SEC-BUTYLBOROHYDRIDE - NEW REAGENT FOR REDUCTION OF CYCLIC AND BICYCLIC KETONES WITH SUPER STEREOSELECTIVITY - REMARKABLY SIMPLE AND PRACTICAL PROCEDURE FOR CONVERSION OF KETONES TO ALCOHOLS IN EXCEPTIONALLY HIGH STEREOCHEMICAL PURITY [J].

BROWN, HC ;

KRISHNAMURTHY, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (20) :7159-+

[3] SYNTHETIC STUDIES ON DAMASCENONES [J].

BUCHI, G ;

WUEST, H .

HELVETICA CHIMICA ACTA, 1971, 54 (07) :1767-&

[4]

BUCHI G, 1972, J AM CHEM SOC, V94, P9128

[5] USEFUL DIENE FOR DIELS-ALDER REACTION [J].

DANISHEFSKY, S ;

KITAHARA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (25) :7807-7808

[6] DIELS-ALDER ROUTE TO CIS-FUSED DELTA-1-3-OCTALONES [J].

DANISHEFSKY, S ;

KITAHARA, T .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (04) :538-539

[7] STRUCTURE AND SYNTHESIS OF DAMASCENONE (TRIMETHYL-2,6,6-TRANS-CROTONOYL-1-CYCLO-HEXADIENE-1,3), ODORIFEROUS CONSTITUENT OF BULGARIAN ROSE OIL [J].

DEMOLE, E ;

ENGGIST, P ;

SAUBERLI, U ;

STOLL, M ;

KOVATS, ES .

HELVETICA CHIMICA ACTA, 1970, 53 (03) :541-&

[8] CHEMICAL STUDY OF BURLEY TOBACCO FLAVOR (NICOTIANA-TABACUM L) .1. VOLATILE TO MEDIUM-VOLATILE CONSTITUENTS (BP LESS-THAN-OR EQUAL-TO 84 DEGREES 0.001 TORR) [J].

DEMOLE, E ;

BERTHET, D .

HELVETICA CHIMICA ACTA, 1972, 55 (06) :1866-+

[9] IDENTIFICATION OF DAMASCENONE AND BETA-DAMASCONE IN BURLEY TOBACCO [J].

DEMOLE, E ;

BERTHET, D .

HELVETICA CHIMICA ACTA, 1971, 54 (02) :681-&

[10] NEUTRAL AROMA CONSTITUENTS IN BURLEY TOBACCO [J].

FUJIMORI, T ;

KASUGA, R ;

MATSUSHITA, H ;

KANEKO, H ;

NOGUCHI, M .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1976, 40 (02) :303-315